Tag Archives: Science

Maxwell’s Demon, Lions and semipermeable membranes

A few weeks ago I went to a talk based on http://arxiv.org/abs/1003.0179. The argument is that in thermodynamics it is wrong to treat particles as indistinguishable. If you have two different kinds of particles in a container, then in principle it is possible to separate them using a semipermeable membrane, and so there is an entropy of mixing, no matter how small the difference is. Why should there be a discontinuity when the difference is reduced to zero?

Talk of semipermeable membranes made me think of the following:
Catching lions in the desert
The thermodynamic method: We construct a semi-permeable membrane which is permeable to everything except lions and sweep it across the desert. (H. Pétard 1938)

It is possible to accept Diek’s argument, thinking of the particles as being physically identical, but each having a unique identifier. The entropy would then be different to what it is normally taken to be, but you also need to think about how the distinguishabilty of the particles might be detected. There would need to be some sort of Maxwell’s demon, reading the identifier for each. There would be an entropy cost to this – according to Landauer’s principle it is when the demon needs to forget what it has read. This would presumably cancel out the difference in entropy in this model.

I once saw a pair of capercaillies in a wildlife park in an enclosure split into two parts. Between the two parts there was a hole which the female could get through, but the male, being considerably bigger could not. Hence the female got to choose whether she spent time with the male or not. So this is a semi-permeable membrane, differentiating one animal from another.  Maybe the lion membrane isn’t so far fetched… But then to distinguish lions from everything else would need more than a hole of a given size, it would need a system which recognised lions – some sort of artificial intelligence.

My conclusion is that the claim that you can in principle find a semipermeable membrane to distinguish two different kinds of particles needs qualifying.  When the difference is substantial it will be a matter of physics, but as the particles become more and more similar, distinguishing them becomes more of a matter of computation – which is thermodynamically different to using physics to distinguish them. This argues against the idea that physical processes can be thought of as computations – Some systems may be thought of as making choices, but a hole which allows some particles through and not others shouldn’t be thought of as a computational device.


Thoughts about the multiverse

The idea of a multiverse has a lot going for it.  In quantum theory, the many worlds interpretation avoids some of the tricky problems of other interpretations.  More generally, the question of why the universe seems to be tuned for life to exist is easier to understand if there are many universes – naturally we will find ourselves in one which is suited to life, but there may be many more which have no life. However, I have my doubts about the benefits of postulating a multiverse.

Karl Popper objected to  Freudian psychology and Marxism because they had an answer to everything.  In particular, if you criticised them, then it couldn’t be because they were wrong – it was because there was a problem with your mind. You had been brainwashed by bourgeois society or were suppressing an event in your past.  I see the many worlds idea as having a similar problem.  Other universes exist, but things are set up in such a way that your mind can’t detect them.

I would look on multiverse ideas more favourably if there was a way to travel between universes. I just don’t buy the idea that things can become separated so that there can never again be any communication between them.  Once it was thought that if mass fell into a black hole then it was gone forever.  But then came Hawking radiation – the mass in a black hole is in fact gradually returned to the rest of the universe.  I’ve also heard  a new postulate of thermodynamics proposed saying that for any two systems there will be some possibility of interaction between them.

Then there’s the question of a Deity.  I’m not convinced that postulating a creator does anything to answer the question of why there is something rather than nothing, or why it seems to be tuned for life to exist.  Some have put forward the multiverse as an alternative to a creator.  I don’t agree with this.  In the Narnia books by C.S. Lewis there is the ‘wood between the worlds’, a place (in Aslan’s country seemingly) from which each of the different worlds can be reached.  If there is a multiverse then I would expect there to be a corresponding ‘wood between the worlds’. Maybe, as in the Narnia books, travel between the worlds is more related to religion than to science. So I see the existence of a multiverse as supporting the possibility of a Deity, rather than arguing against it.

Does it matter whether God plays dice?

There seems to be a consensus that quantum theory has to be intrinsically random, as well as various claims that you can’t have a classical model of quantum theory and that you can have a local model of quantum theory, as long as you’re willing to sacrifice realism.

I think that much of this is poorly thought out. I’ve written about this at http://quantropy.org/19/, but essentially, it is always possible to replace intrinsic randomness in a model by pseudo-randomness (possibly some sort of chaotic system), without affecting the model greatly. And what does realism mean? If it means determinism as opposed to randomness, well randomness certainly doesn’t help you to keep locality. In the end realism doesn’t seem to mean anything very much.

As for the claim that quantum theory can’t have a classical model, this seems incoherent to me. You can do calculations in quantum theory, and these agree closely with experiment. Calculations can be performed on a computer, and a computer (in the abstract) is a classical system. So you have a classical model.

You can read more at http://quantropy.org/19/